Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction | Zendy

ShaoChi Lee | Zendy; Lin Guo | Zendy; Magnus Rueping | Zendy

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Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction

Author(s) -

ShaoChi Lee,

Lin Guo,

Magnus Rueping

Publication year - 2019

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c9cc07558e

Subject(s) - hydroacylation , catalysis , nickel , chemistry , coupling (piping) , coupling reaction , combinatorial chemistry , suzuki reaction , organic chemistry , materials science , palladium , rhodium , metallurgy

The first nickel-catalyzed intramolecular hydroacylation/Suzuki cross coupling cascade of o-allylbenzaldehydes with a broad range of phenylboronic acid neopentyl glycol esters has been developed. This strategy shows high regioselectivity and step economy in the construction of two C-C bonds via aldehyde C-H bond activation, affording valuable indanones with high efficiency.

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