Open AccessEnantioselective organocatalytic activation of vinylidene–quinone methides (VQMs)
Author(s) -
Jean Rodriguez,
Damien Bonne
Publication year - 2019
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c9cc05097c
Subject(s) - enantioselective synthesis , electrophile , organocatalysis , quinone , chemistry , reagent , reactivity (psychology) , chirality (physics) , combinatorial chemistry , organic chemistry , catalysis , physics , medicine , chiral symmetry breaking , alternative medicine , quantum mechanics , quark , nambu–jona lasinio model , pathology
Vinylidene–quinone methides (VQMs) are highly electrophilic chiral reagents that can be generated in situ from 2-(phenylethynyl)phenols. Their specific reactivity has revealed innovative strategies notably for the control of axial chirality.
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