Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES | Zendy

Dinis O. Abranches | Zendy; Mónia A. R. Martins | Zendy; Liliana P. Silva | Zendy; Nicolas Schaeffer | Zendy; Simão P. Pinho | Zendy; João A. P. Coutinho | Zendy

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Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES

Author(s) -

Dinis O. Abranches,

Mónia A. R. Martins,

Liliana P. Silva,

Nicolas Schaeffer,

Simão P. Pinho,

João A. P. Coutinho

Publication year - 2019

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c9cc04846d

Subject(s) - chemistry , ionic bonding , thymol , eutectic system , hydrogen bond , ionic compound , ionic liquid , inorganic chemistry , medicinal chemistry , organic chemistry , polymer chemistry , ion , molecule , chromatography , alloy , essential oil , catalysis

Mixtures of non-ionic compounds have been reported as DES but most are just ideal mixtures. In the thymol-menthol system, an abnormal strong interaction was identified stemming from the acidity difference of the phenolic and aliphatic hydroxyl groups. This type of interaction is found to be the key to prepare non-ionic DES, that may be classified as type V.

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