Open Accessπ Complexes of P^P and P^N chelated gold(i )
Author(s) -
Miquel Navarro,
Alberto Toledo,
Maximilian Joost,
Abderrahmane Amgoune,
Sonia MalletLadeira,
Didier Bourissou
Publication year - 2019
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c9cc04266k
Subject(s) - chelation , chemistry , medicinal chemistry , stereochemistry , inorganic chemistry
Tricoordinate gold(i) π-complexes containing P-based chelating ligands (P^P and P^N) were prepared. The structure of the gold(i) styrene complexes has been analysed in detail based on NMR and XRD data. The P^N complex is a competent catalyst for indole alkylation. The reaction proceeds with complete C3 and Markovnikov selectivity.
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