Protein film electrochemical EPR spectroscopy as a technique to investigate redox reactions in biomolecules | Zendy

Kaltum Abdiaziz | Zendy; Enrico Salvadori | Zendy; Katarzyna P. Sokol | Zendy; Erwin Reisner | Zendy; Maxie M. Roessler | Zendy

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Protein film electrochemical EPR spectroscopy as a technique to investigate redox reactions in biomolecules

Author(s) -

Kaltum Abdiaziz,

Enrico Salvadori,

Katarzyna P. Sokol,

Erwin Reisner,

Maxie M. Roessler

Publication year - 2019

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c9cc03212f

Subject(s) - redox , electron paramagnetic resonance , biomolecule , electrochemistry , chemistry , spectroscopy , photochemistry , materials science , nanotechnology , inorganic chemistry , electrode , nuclear magnetic resonance , physics , quantum mechanics

Redox reactions and paramagnetic intermediates are ubiquitous in biological chemistry. We report a new method, protein film electrochemical electron paramagnetic resonance spectroscopy (PFE-EPR), that enables the direct and accurate potential control of proteins on the electrode surface for both electrochemical and EPR spectroscopic characterisation of their redox centres.

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