Phenolics isolation from bio-oil using the metal–organic framework MIL-53(Al) as a highly selective adsorbent | Zendy

Chunmei Jia | Zendy; Bart Bueken | Zendy; Francisco G. Cirujano | Zendy; Kevin M. Van Geem | Zendy; Dirk De Vos | Zendy

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Phenolics isolation from bio-oil using the metal–organic framework MIL-53(Al) as a highly selective adsorbent

Author(s) -

Chunmei Jia,

Bart Bueken,

Francisco G. Cirujano,

Kevin M. Van Geem,

Dirk De Vos

Publication year - 2019

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c9cc02177a

Subject(s) - pyrolysis , adsorption , refining (metallurgy) , isolation (microbiology) , metal organic framework , chemistry , metal , chemical engineering , organic chemistry , microbiology and biotechnology , biology , engineering

By using flexible metal organic frameworks such as MIL-53(Al), the selective uptake of 4-methylguaiacol was achieved from a simulated bio-oil (40 wt%). Similar high uptake capacity of phenolics (27 wt%) was observed from a real pyrolysis bio-oil, with good selectivity towards a variety of phenolics, e.g. guaiacol, 4-methylguaiacol and catechol.

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