Carbonization of covalent triazine-based frameworks via ionic liquid induction | Zendy

Jiangtao Jia | Zendy; Zhijie Chen | Zendy; Youssef Belmabkhout | Zendy; Karim Adil | Zendy; Prashant M. Bhatt | Zendy; Vera Solovyeva | Zendy; Osama Shekhah | Zendy; Mohamed Eddaoudi | Zendy

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Carbonization of covalent triazine-based frameworks via ionic liquid induction

Author(s) -

Jiangtao Jia,

Zhijie Chen,

Youssef Belmabkhout,

Karim Adil,

Prashant M. Bhatt,

Vera Solovyeva,

Osama Shekhah,

Mohamed Eddaoudi

Publication year - 2018

Publication title -

journal of materials chemistry a

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.637

H-Index - 212

eISSN - 2050-7488

pISSN - 2050-7496

DOI - 10.1039/c8ta05583a

Subject(s) - carbonization , porosity , ionic liquid , covalent bond , block (permutation group theory) , triazine , polymer , ionic bonding , chemical engineering , materials science , chemistry , polymer chemistry , organic chemistry , ion , adsorption , catalysis , engineering , mathematics , geometry

A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid were allowed to alter/enhance the Brunauer–Emmett–Teller (BET) surface areas of the POPs in the range from 760 to 1560 m2 g−1. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

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