Open AccessA twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands
Author(s) -
Akira Nagai,
Takashi Nakamura,
Tatsuya Nabeshima
Publication year - 2019
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c8cc09643k
Subject(s) - palladium , chemistry , pyridine , derivative (finance) , molecule , combinatorial chemistry , stereochemistry , crystallography , medicinal chemistry , catalysis , organic chemistry , financial economics , economics
A macrocyclic hexanuclear palladium complex, which accumulates coordination sites on metals inside the cavity, was synthesized. The macrocycle was found to take a uniquely-twisted C2-symmetric conformation when six molecules of a bulky pyridine derivative coordinated to the palladium.
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