The Ouzo effect to selectively assemble molybdenum clusters into nanomarbles or nanocapsules with increased HER activity | Zendy

Flavien Sciortino | Zendy; Jérôme Cuny | Zendy; Fabien Grasset | Zendy; Corinne Lagrost | Zendy; Pierric Lemoine | Zendy; Alain Moréac | Zendy; Yann Molard | Zendy; Toshiaki Takei | Zendy; Stéphane Cordier | Zendy; Soizic Chevance | Zendy; Fabienne Gauffre | Zendy

Open Access

The Ouzo effect to selectively assemble molybdenum clusters into nanomarbles or nanocapsules with increased HER activity

Author(s) -

Flavien Sciortino,

Jérôme Cuny,

Fabien Grasset,

Corinne Lagrost,

Pierric Lemoine,

Alain Moréac,

Yann Molard,

Toshiaki Takei,

Stéphane Cordier,

Soizic Chevance,

Fabienne Gauffre

Publication year - 2018

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c8cc07402j

Subject(s) - nanocapsules , molybdenum , solubility , chemistry , chemical engineering , nanotechnology , materials science , organic chemistry , nanoparticle , engineering

Metal cluster nanoparticles are obtained by simple solvent shifting called the Ouzo effect. Remarkably, the assembly of [{Mo6Br8}L6]2- (L = Br- or NCS-) cluster units can be directed into nanomarbles or nanocapsules depending on the cluster chemistry. When deposited on electrodes, these nanoparticles show good activities in electrochemical water splitting under mild conditions.

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