Diverse catalytic reactivity of a dearomatized PN3P*–nickel hydride pincer complex towards CO2 reduction | Zendy

Huaifeng Li | Zendy; Théo P. Gonçalves | Zendy; Qianyi Zhao | Zendy; Dirong Gong | Zendy; Zhiping Lai | Zendy; Zhixiang Wang | Zendy; Junrong Zheng | Zendy; KuoWei Huang | Zendy

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Diverse catalytic reactivity of a dearomatized PN³P*–nickel hydride pincer complex towards CO₂ reduction

Author(s) -

Huaifeng Li,

Théo P. Gonçalves,

Qianyi Zhao,

Dirong Gong,

Zhiping Lai,

Zhixiang Wang,

Junrong Zheng,

KuoWei Huang

Publication year - 2018

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c8cc05948a

Subject(s) - nickel , hydride , hydrosilylation , catalysis , chemistry , pincer movement , methanol , reactivity (psychology) , hydrogen , medicinal chemistry , organic chemistry , medicine , alternative medicine , pathology

A dearomatized PN3P*-nickel hydride complex has been prepared using an oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selective methylation and formylation of amines with CO2 were demonstrated by such a PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.

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