Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5containing ion pairs and the application in fluorinations | Zendy

Magnus Rueping | Zendy; Pavlo Nikolaienko | Zendy; Yury Lebedev | Zendy; Alina Adams | Zendy

Open Access

Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF₅containing ion pairs and the application in fluorinations

Author(s) -

Magnus Rueping,

Pavlo Nikolaienko,

Yury Lebedev,

Alina Adams

Publication year - 2017

Publication title -

green chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.221

H-Index - 221

eISSN - 1463-9270

pISSN - 1463-9262

DOI - 10.1039/c7gc00877e

Subject(s) - sulfur hexafluoride , sulfur , chemistry , inorganic chemistry , greenhouse gas , metal , ion , radiochemistry , organic chemistry , biology , ecology

A protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed. The reaction yields solid ion pairs consisting of donor dications and SF5-anions which can be effectively used in fluorination reactions

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