Intriguing C–H⋯Cu interactions in bis-(phenanthroline)Cu(i) redox mediators for dye-sensitized solar cells | Zendy

Alessia Colombo | Zendy; Rachele Ossola | Zendy; Mirko Magni | Zendy; Dominique Roberto | Zendy; Denis Jacquemin | Zendy; Carlo Castellano | Zendy; Francesco Demartin | Zendy; Claudia Dragonetti | Zendy

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Intriguing C–H⋯Cu interactions in bis-(phenanthroline)Cu(i) redox mediators for dye-sensitized solar cells

Author(s) -

Alessia Colombo,

Rachele Ossola,

Mirko Magni,

Dominique Roberto,

Denis Jacquemin,

Carlo Castellano,

Francesco Demartin,

Claudia Dragonetti

Publication year - 2017

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c7dt04045h

Subject(s) - phenanthroline , redox , copper , chemistry , dye sensitized solar cell , atom (system on chip) , medicinal chemistry , photochemistry , stereochemistry , crystallography , inorganic chemistry , organic chemistry , electrode , electrolyte , computer science , embedded system

We have synthesized and characterized a series of bis-(phenanthroline)Cu(i) complexes of interest as redox mediators for dye-sensitized solar cells. This study led to the discovery of intriguing anagostic interactions between the hydrogen atom and the copper center as evidenced by X-ray diffraction studies on a single crystal. Remarkably, an anagostic interaction was found between a H atom of a methyl group and a copper site.

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