Energy landscapes and dynamics of glycine on Cu(110)
Author(s) -
Marco Sacchi,
David J. Wales,
Stephen J. Jenkins
Publication year - 2017
Publication title -
physical chemistry chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.053
H-Index - 239
eISSN - 1463-9084
pISSN - 1463-9076
DOI - 10.1039/c7cp02716h
Subject(s) - glycine , supramolecular chemistry , monolayer , chirality (physics) , chemical physics , self assembled monolayer , metal , self assembly , adsorption , nanotechnology , chemistry , supramolecular chirality , mechanism (biology) , crystallography , materials science , amino acid , crystal structure , physics , organic chemistry , biochemistry , nambu–jona lasinio model , chiral symmetry breaking , quantum mechanics , quark
Amino acids adsorbed on single-crystal metal surfaces have emerged as prototypical systems for exploring the properties that govern the development of long-range chirality in self-assembled monolayers (SAM) and supramolecular 2D networks. In this study, we characterise the self-assembly mechanism for glycine on the Cu(110) surface. This process occurs on a time scale that is too fast for most atomically resolved microscopic techniques, so the mechanism we propose here provides new insight for an important unexplored surface phenomenon.
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