Surface acid–base catalytic activity of ZIF-8 revealed by super-resolution fluorescence microscopy | Zendy

A. V. Kubarev | Zendy; Maarten B. J. Roeffaers | Zendy

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Surface acid–base catalytic activity of ZIF-8 revealed by super-resolution fluorescence microscopy

Author(s) -

A. V. Kubarev,

Maarten B. J. Roeffaers

Publication year - 2017

Publication title -

crystengcomm

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.813

H-Index - 132

ISSN - 1466-8033

DOI - 10.1039/c7ce00074j

Subject(s) - fluorescence , fluorescence microscope , microscopy , catalysis , oleic acid , resolution (logic) , chemistry , porosity , high resolution , materials science , chemical engineering , biochemistry , organic chemistry , optics , computer science , physics , geology , engineering , artificial intelligence , remote sensing

We investigated the catalytic activity of ZIF-8 in the fluorescein diacetate hydrolysis via super-resolution fluorescence microscopy. Acid-base activity is detected only on the outer surface and crystalline defects. Oleic acid etching introduces extra porosity and allows for catalytic conversions inside of the crystals, but leads to overall activity loss.status: publishe

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