Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions | Zendy

José M. Gil-Negrete | Zendy; José Pérez Sestelo | Zendy; Luis A. Sarandeses | Zendy

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Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions

Author(s) -

José M. Gil-Negrete,

José Pérez Sestelo,

Luis A. Sarandeses

Publication year - 2018

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c7cc09344f

Subject(s) - palladium , reagent , reactivity (psychology) , electrophile , catalysis , pyridine , chemistry , yield (engineering) , coupling reaction , combinatorial chemistry , organic chemistry , materials science , medicine , alternative medicine , pathology , metallurgy

Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R 3 In(DMAP) complexes are obtained from the corresponding solution of R 3 In in quantitative yield and can be stored for up to several weeks. These reagents show excellent reactivity in palladium-catalyzed cross-coupling reactions with organic electrophiles.

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