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Self-organization of amino-acid-derived NDI assemblies into a nanofibrillar superstructure with humidity sensitive n-type semiconducting properties
Author(s) -
Marco Squillaci,
Grzegorz Markiewicz,
Anna Walczak,
Artur Ciesielski,
Artur R. Stefankiewicz,
Paolo Samorı́
Publication year - 2017
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c7cc04822j
Subject(s) - superstructure , supramolecular chemistry , covalent bond , polymerization , polymer , materials science , atomic force microscopy , self assembly , chemical engineering , spectroscopy , solid state , polymer chemistry , nanotechnology , chemistry , crystallography , organic chemistry , crystal structure , composite material , physics , engineering , oceanography , quantum mechanics , geology
The hierarchical self-assembly of l-tyrosine substituted naphthalenediimide has been explored in solution by NMR spectroscopy and in the solid-state by atomic force microscopy. Spontaneous non-covalent polymerisation led to the formation of a three-dimensional fibre-like supramolecular polymer with n-type semiconducting properties.

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