Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex | Zendy

Allan R. Petersen | Zendy; Andrew J. P. White | Zendy; George J. P. Britovsek | Zendy

Open Access

Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex

Author(s) -

Allan R. Petersen,

Andrew J. P. White,

George J. P. Britovsek

Publication year - 2016

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c6dt01691j

Subject(s) - palladium , platinum , aminal , chemistry , acetone , reactivity (psychology) , formaldehyde , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology

The 6,6''-diaminoterpyridine palladium(ii) methylperoxo complex eliminates methyl hydroperoxide and reacts with acetone to form a novel hemi-aminal palladium complex, whereas the analogous platinum(ii) complex generates formaldehyde and a platinum(ii) hydroxo complex.

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