Trigonal prismatic metal complexes: a not so rare coordination geometry? | Zendy

Leighton J. Alcock | Zendy; Germán Cavigliasso | Zendy; Anthony C. Willis | Zendy; Robert Stranger | Zendy; Stephen F. Ralph | Zendy

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Trigonal prismatic metal complexes: a not so rare coordination geometry?

Author(s) -

Leighton J. Alcock,

Germán Cavigliasso,

Anthony C. Willis,

Robert Stranger,

Stephen F. Ralph

Publication year - 2016

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c6dt01176d

Subject(s) - trigonal prismatic molecular geometry , ligand (biochemistry) , trigonal crystal system , crystallography , metal , coordination geometry , geometry , chemistry , molecular geometry , solid state , bond length , materials science , crystal structure , molecule , hydrogen bond , mathematics , octahedron , biochemistry , receptor , organic chemistry

The solid state structures of two metal complexes of a hexaamine macrobicyclic ligand, in which the metal ion has an exact trigonal prismatic geometry, have been determined. Theoretical calculations showed this is the most stable geometry for d(0), d(10) and high spin d(5) metal complexes of the ligand with M-N bond distances >∼2.35 Å.

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