On the Cl⋯C halogen bond: a rotational study of CF3Cl–CO | Zendy

Walther Camináti | Zendy; Luca Evangelisti | Zendy; Gang Feng | Zendy; B. M. Giuliano | Zendy; Qian Gou | Zendy; Sonia Melandri | Zendy; JensUwe Grabow | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

On the Cl⋯C halogen bond: a rotational study of CF₃Cl–CO

Author(s) -

Walther Camináti,

Luca Evangelisti,

Gang Feng,

B. M. Giuliano,

Qian Gou,

Sonia Melandri,

JensUwe Grabow

Publication year - 2016

Publication title -

physical chemistry chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.053

H-Index - 239

eISSN - 1463-9084

pISSN - 1463-9076

DOI - 10.1039/c6cp01059h

Subject(s) - isotopologue , rotational spectroscopy , chemistry , quadrupole , halogen , bond dissociation energy , halogen bond , fourier transform , adduct , rotational transition , rotational energy , dissociation (chemistry) , rotational–vibrational spectroscopy , spectral line , supersonic speed , atomic physics , computational chemistry , molecule , physics , thermodynamics , organic chemistry , angular momentum , alkyl , quantum mechanics , astronomy

The rotational spectra of two isotopologues (CF3(35)Cl-CO and CF3(37)Cl-CO) of the CF3Cl-CO adduct have been investigated and analyzed using supersonic-jet Fourier transform microwave spectroscopy, and found to have the features of a symmetric top. Rotational, centrifugal distortion, and nuclear quadrupole ((35)Cl and (37)Cl) coupling constants have been precisely obtained from high-resolution measurements. The two subunits of the complex are held together via a ClC halogen bond interaction. Information on the internal dynamics and the dissociation energy of the complex is provided.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research