Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system | Zendy

Jamie L. Manson | Zendy; John A. Schlueter | Zendy; Kerry E. Garrett | Zendy; Paul Goddard | Zendy; Tom Lancaster | Zendy; Johannes S. Möller | Zendy; Stephen J. Blundell | Zendy; Andrew J. Steele | Zendy; Isabel Franke | Zendy; F. L. Pratt | Zendy; John Singleton | Zendy; Jesper Bendix | Zendy; Saul H. Lapidus | Zendy; M. Uhlarz | Zendy; Oscar Ayala-Valenzuela | Zendy; R. McDonald | Zendy; Mary Gurak | Zendy; C. Baines | Zendy

Open Access

Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 − x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system

Author(s) -

Jamie L. Manson,

John A. Schlueter,

Kerry E. Garrett,

Paul Goddard,

Tom Lancaster,

Johannes S. Möller,

Stephen J. Blundell,

Andrew J. Steele,

Isabel Franke,

F. L. Pratt,

John Singleton,

Jesper Bendix,

Saul H. Lapidus,

M. Uhlarz,

Oscar Ayala-Valenzuela,

R. McDonald,

Mary Gurak,

C. Baines

Publication year - 2016

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c6cc05873f

Subject(s) - crystallography , bimetallic strip , x ray crystallography , chemistry , pyrazine , materials science , analytical chemistry (journal) , stereochemistry , metal , diffraction , physics , organic chemistry , optics , chromatography

The title compounds are bimetallic MOFs containing [Cu(pyz) 2 ] 2+ square lattices linked by MF 6 n- octahedra. In each, only the Cu 2+ spins exhibit long-range magnetic order below 3.5 K (M = V 4+ ) and 2.6 K (M = Ga 3+ ). The V 4+ spins remain disordered down to 0.5 K.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research