Preparation of dipyrrins from F-BODIPYs by treatment with methanesulfonic acids
Author(s) -
J. Urieta,
Beatriz Lora Maroto,
Florencio Moreno,
Antonia R. Agarrabeitia,
María J. Ortiz,
Santiago de la Moya Cerero
Publication year - 2015
Publication title -
rsc advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.746
H-Index - 148
ISSN - 2046-2069
DOI - 10.1039/c5ra14914b
Subject(s) - methanesulfonic acid , chemistry , combinatorial chemistry , organic chemistry
An alternative metal-free soft procedure for the preparation of dipyrrins from F-BODIPYs is reported. The new method makes possible to obtain certain dipyrrin derivatives that were unaccessible from F-BODIPYs to date. To demonstrate the ability of the new procedure, dipyrrins having highly reactive groups, such as chloro, cyano or acetoxyl, have been easily obtained from the corresponding F-BODIPY, which shows the synthetic utility of the reported methodology
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