Self-assembled construction of a sheet-type coordination polymer bearing cationic M2L4 cages: creation of channel-like space for removal of ClO4− and NO3− from aqueous solutions | Zendy

Eriko Sone | Zendy; Moeko Sato | Zendy; Katsunori Yamanishi | Zendy; Chihiro Kamio | Zendy; Hiroyuki Takemoto | Zendy; Mitsuru Kondo | Zendy

Open Access

Self-assembled construction of a sheet-type coordination polymer bearing cationic M₂L₄ cages: creation of channel-like space for removal of ClO₄⁻ and NO₃⁻ from aqueous solutions

Author(s) -

Eriko Sone,

Moeko Sato,

Katsunori Yamanishi,

Chihiro Kamio,

Hiroyuki Takemoto,

Mitsuru Kondo

Publication year - 2015

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c5dt03602j

Subject(s) - cationic polymerization , bearing (navigation) , space (punctuation) , polymer , crystallography , materials science , type (biology) , chemistry , polymer chemistry , nanotechnology , physics , composite material , computer science , geology , operating system , paleontology , astronomy

Treatment of CuCl2 with a bis-benzimidazole-type ligand, p-bbiteb, afforded a new 2D coordination polymer bearing cationic Cu2L4 cages on the sheet framework. The regular arrangement of the cages created channel-like space for anions. The compound removed ClO4(-) and NO3(-) from aqueous solutions by exchange with Cl(-) in the channels.

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