A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates | Zendy

Stef Vanhaecht | Zendy; Jeroen Jacobs | Zendy; Luc Van Meervelt | Zendy; Tatja. ParacVogt | Zendy

Open Access

A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates

Author(s) -

Stef Vanhaecht,

Jeroen Jacobs,

Luc Van Meervelt,

Tatja. ParacVogt

Publication year - 2015

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c5dt03559g

Subject(s) - surface modification , grafting , organic molecules , materials science , molecule , nanotechnology , combinatorial chemistry , polymer chemistry , chemistry , organic chemistry , polymer , composite material

A new azide functionalized Anderson polyoxometalate was synthesized, fully characterized and subsequently used as a building block for further POM post-functionalization with organic compounds through a copper catalyzed azide-alkyne cycloaddition (CuAAC) reaction. Optimization of the reaction conditions led to an efficient, fast, convenient and versatile POM coupling method.

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