C–H and H–H bond activation via ligand dearomatization/rearomatization of a PN3P-rhodium(i) complex | Zendy

Yuan Wang | Zendy; Bin Zheng | Zendy; Yupeng Pan | Zendy; ChengLing Pan | Zendy; Lipeng He | Zendy; KuoWei Huang | Zendy

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C–H and H–H bond activation via ligand dearomatization/rearomatization of a PN³P-rhodium(i) complex

Author(s) -

Yuan Wang,

Bin Zheng,

Yupeng Pan,

ChengLing Pan,

Lipeng He,

KuoWei Huang

Publication year - 2015

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c5dt00787a

Subject(s) - rhodium , chemistry , ligand (biochemistry) , stereochemistry , medicinal chemistry , catalysis , organic chemistry , receptor , biochemistry

A neutral complex PN(3)P-Rh(I)Cl (2) was prepared from a reaction of the PN(3)P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H-H and C(sp(2))-H activation reactions can be achieved through the deprotonation/reprotonation of one of the N-H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.

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