Probing of chain conformations in conjugated polymer nanoparticles by electron spin resonance spectroscopy | Zendy

Christian Hintze | Zendy; Falk Schütze | Zendy; Malte Drescher | Zendy; Stefan Mecking | Zendy

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Probing of chain conformations in conjugated polymer nanoparticles by electron spin resonance spectroscopy

Author(s) -

Christian Hintze,

Falk Schütze,

Malte Drescher,

Stefan Mecking

Publication year - 2015

Publication title -

physical chemistry chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.053

H-Index - 239

eISSN - 1463-9084

pISSN - 1463-9076

DOI - 10.1039/c5cp05749c

Subject(s) - conjugated system , polymer , electron paramagnetic resonance , nanoparticle , spectroscopy , chain (unit) , materials science , chemical physics , resonance (particle physics) , electron , chemistry , nuclear magnetic resonance , nanotechnology , organic chemistry , atomic physics , physics , astronomy , quantum mechanics

In the case of conjugated polymer chains usually considered as rigid or stiff, it is an open question how the individual chains adopt their conformation inside nanoparticles. Here, the conformation of such a rigid conjugated polymer chain is elucidated for the first time. For this purpose, electron paramagnetic resonance spectroscopy as a method allowing for a direct observation is established.

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