Ammonium–crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster–metal coordination polymer with enhanced NLO properties | Zendy

Jinfang Zhang | Zendy; Jia Ding | Zendy; Mark G. Humphrey | Zendy; Suci Meng | Zendy; Michael J. Zaworotko | Zendy; Marie P. Cifuentes | Zendy; Chi Zhang | Zendy

Open Access

Ammonium–crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster–metal coordination polymer with enhanced NLO properties

Author(s) -

Jinfang Zhang,

Jia Ding,

Mark G. Humphrey,

Suci Meng,

Michael J. Zaworotko,

Marie P. Cifuentes,

Chi Zhang

Publication year - 2016

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c5cc10076c

Subject(s) - crown ether , supramolecular chemistry , ammonium , metal , ether , coordination polymer , polymer chemistry , polymer , chemistry , crown (dentistry) , coordination complex , materials science , combinatorial chemistry , nanotechnology , crystallography , organic chemistry , ion , crystal structure , composite material

An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3](+) with different connection environments, pentanuclear clusters [WS4Cu4](2+), and Cu(+) building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.

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