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Fullerene-free small molecule organic solar cells with a high open circuit voltage of 1.15 V
Author(s) -
Wang Ni,
Miaomiao Li,
Bin Kan,
Feng Liu,
Xiangjian Wan,
Qian Zhang,
Hongtao Zhang,
Thomas P. Russell,
Yongsheng Chen
Publication year - 2015
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c5cc07973j
Subject(s) - open circuit voltage , fullerene , organic solar cell , small molecule , molecule , voltage , materials science , chemistry , nanotechnology , optoelectronics , photochemistry , organic chemistry , physics , biochemistry , quantum mechanics , polymer
A new small molecule named DTBTF with thiobarbituric acid as a terminal group was designed and synthesized as an acceptor for organic photovoltaic applications. DTBTF exhibits strong absorption in the visible region, and a relatively high lying LUMO energy level (-3.62 eV). All-small-molecule organic solar cells based on DR3TSBDT:DTBTF blend films show a considerable PCE of 3.84% with a high V(oc) of 1.15 V.

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