Open AccessReaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids
Author(s) -
Sara Vidal,
Marta Izquierdo,
Salvatore Filippone,
Fulvio G. Brunetti,
Nazario Martı́n
Publication year - 2015
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c5cc07602a
Subject(s) - characterization (materials science) , chemistry , nanotechnology , combinatorial chemistry , materials science
The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same trend (a > b > c > d) to that observed for pristine C70 (α > β > γ > δ).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom