l-Aspartate links for stable sodium metal–organic frameworks | Zendy

Peter Siman | Zendy; Christopher A. Trickett | Zendy; Hiroyasu Furukawa | Zendy; Omar M. Yaghi | Zendy

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l-Aspartate links for stable sodium metal–organic frameworks

Author(s) -

Peter Siman,

Christopher A. Trickett,

Hiroyasu Furukawa,

Omar M. Yaghi

Publication year - 2015

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c5cc07578e

Subject(s) - carboxylate , linker , metal organic framework , sodium , chemistry , solvent , oxide , metal , combinatorial chemistry , inorganic chemistry , organic chemistry , computer science , adsorption , operating system

Metal-organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

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