Homogeneous liquid–liquid extraction of metal ions with non-fluorinated bis(2-ethylhexyl)phosphate ionic liquids having a lower critical solution temperature in combination with water | Zendy

Daphne Depuydt | Zendy; Liwang Liu | Zendy; Christ Glorieux | Zendy; Wim Dehaen | Zendy; Koen Binnemans | Zendy

Open Access

Homogeneous liquid–liquid extraction of metal ions with non-fluorinated bis(2-ethylhexyl)phosphate ionic liquids having a lower critical solution temperature in combination with water

Author(s) -

Daphne Depuydt,

Liwang Liu,

Christ Glorieux,

Wim Dehaen,

Koen Binnemans

Publication year - 2015

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c5cc05649g

Subject(s) - ionic liquid , extraction (chemistry) , phosphate , homogeneous , ion , inorganic chemistry , chemistry , ether , metal ions in aqueous solution , lower critical solution temperature , liquid–liquid extraction , materials science , organic chemistry , catalysis , thermodynamics , polymer , physics , copolymer

Ionic liquids with an ether-functionalised cation and the bis(2-ethylhexyl)phosphate anion show thermomorphic behaviour in water, with a lower critical solution temperature. These ionic liquids are useful for homogeneous liquid-liquid extraction of first-row (3d) transition metals.

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