Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors | Zendy

Xueliang Shi | Zendy; Sangsu Lee | Zendy; Minjung Son | Zendy; Bin Zheng | Zendy; Jingjing Chang | Zendy; Linzhi Jing | Zendy; KuoWei Huang | Zendy; Dongho Kim | Zendy; Chunyan Chi | Zendy

Open Access

Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors

Author(s) -

Xueliang Shi,

Sangsu Lee,

Minjung Son,

Bin Zheng,

Jingjing Chang,

Linzhi Jing,

KuoWei Huang,

Dongho Kim,

Chunyan Chi

Publication year - 2015

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c5cc04243g

Subject(s) - thiophene , aromaticity , ground state , chemistry , molecule , computational chemistry , stereochemistry , organic chemistry , physics , atomic physics

A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS.

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