Tuning the depth of bowl-shaped phosphine hosts: capsule and pseudo-cage architectures in host–guest complexes with C60 fullerene | Zendy

Masaki Yamamura | Zendy; Kimiya Sukegawa | Zendy; Tatsuya Nabeshima | Zendy

Open Access

Tuning the depth of bowl-shaped phosphine hosts: capsule and pseudo-cage architectures in host–guest complexes with C₆₀ fullerene

Author(s) -

Masaki Yamamura,

Kimiya Sukegawa,

Tatsuya Nabeshima

Publication year - 2015

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c5cc04194e

Subject(s) - cage , substituent , fullerene , molecule , host (biology) , phosphine , chemistry , capsule , crystallography , stereochemistry , nanotechnology , materials science , organic chemistry , biology , paleontology , mathematics , combinatorics , catalysis , ecology

Bowl-shaped phosphine molecules, whose bowl geometry can be controlled by a variation of the axial substituent, were synthesized, and used as host molecules to encapsulate C60. Host molecules with relatively shallow bowls formed a chiral capsule, while hosts with deeper bowls formed an achiral pseudo-cage.

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