Porphyrinic supramolecular daisy chains incorporating pillar[5]arene–viologen host–guest interactions | Zendy

Maher Fathalla | Zendy; Nathan L. Strutt | Zendy; Srinivasan Sampath | Zendy; Khabiboulakh Katsiev | Zendy; Karel J. Hartlieb | Zendy; Osman M. Bakr | Zendy; J. Fraser Stoddart | Zendy

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Porphyrinic supramolecular daisy chains incorporating pillar[5]arene–viologen host–guest interactions

Author(s) -

Maher Fathalla,

Nathan L. Strutt,

Srinivasan Sampath,

Khabiboulakh Katsiev,

Karel J. Hartlieb,

Osman M. Bakr,

J. Fraser Stoddart

Publication year - 2015

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c5cc03717d

Subject(s) - viologen , supramolecular chemistry , pillar , supramolecular assembly , dichloromethane , amphiphile , chemistry , porphyrin , host–guest chemistry , daisy chain , nanotechnology , materials science , photochemistry , molecule , copolymer , organic chemistry , polymer , structural engineering , engineering , solvent , computer science , computer hardware

A porphyrin functionalised with pillar[5]arene and a viologen at its 5- and 15-meso positions assembles in a head-to-tail manner, producing linear supramolecular daisy chains in dichloromethane. At high concentrations, it forms an organogel which has been investigated by electron microscopy and rheological measurements, paving the way for the preparation of other functional supramolecular assemblies which harness viologen⊂pillararene host-guest interactions.

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