A novel 1,8-naphthalimide derivative with an open space for an anion: unique fluorescence behaviour depending on the binding anion's electrophilic properties | Zendy

Hironori Izawa | Zendy; Shoji Nishino | Zendy; Masato Sumita | Zendy; Masaaki Akamatsu | Zendy; Kenji Morihashi | Zendy; Shinsuke Ifuku | Zendy; Minoru Morimoto | Zendy; Hiroyuki Saimoto | Zendy

Open Access

A novel 1,8-naphthalimide derivative with an open space for an anion: unique fluorescence behaviour depending on the binding anion's electrophilic properties

Author(s) -

Hironori Izawa,

Shoji Nishino,

Masato Sumita,

Masaaki Akamatsu,

Kenji Morihashi,

Shinsuke Ifuku,

Minoru Morimoto,

Hiroyuki Saimoto

Publication year - 2015

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c5cc01709b

Subject(s) - electrophile , derivative (finance) , ion , fluorescence , chemistry , combinatorial chemistry , organic chemistry , physics , quantum mechanics , financial economics , economics , catalysis

We have designed a novel 1,8-naphthalimide derivative with an open space for an anion. Computational calculation has predicted that the space could trap various anion species and photo-induced charge transfer depending on the anion's electrophilic properties. Indeed, the fluorescence behaviour of the 1,8-naphthalimide derivative complexes with each anion is consistent with the computational prediction.

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