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In situ photogalvanic acceleration of optofluidic kinetics: a new paradigm for advanced photocatalytic technologies
Author(s) -
Huizhi Wang,
Xiaojiao Luo,
Michael K.H. Leung,
Dennis Y.C. Leung,
Zhiyong Tang,
Hailiang Wang,
Rafael Luque,
Jin Xuan
Publication year - 2014
Publication title -
rsc advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.746
H-Index - 148
ISSN - 2046-2069
DOI - 10.1039/c4ra14032j
Subject(s) - photocatalysis , methylene blue , acceleration , reaction rate constant , kinetics , in situ , materials science , photochemistry , optoelectronics , nanotechnology , chemistry , physics , catalysis , organic chemistry , classical mechanics
A multiscale-designed optofluidic reactor is demonstrated in this work, featuring an overall reaction rate constant of 1.32 s−1 for photocatalytic decolourization of methylene blue, which is an order of magnitude higher as compared to literature records. A novel performance-enhancement mechanism of microscale in situ photogalvanic acceleration was found to be the main reason for the superior optofluidic performance in the photocatalytic degradation of dyes as a model reaction.No Full Tex

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