Efficient removal of perchlorate ion from water by a water-insoluble M2L4 type compound | Zendy

Masaru Mochizuki | Zendy; Tatsunari Inoue | Zendy; Katsunori Yamanishi | Zendy; Shiori Koike | Zendy; Mitsuru Kondo | Zendy; Liang Zhang | Zendy; Hiromi Aoki | Zendy

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Efficient removal of perchlorate ion from water by a water-insoluble M₂L₄ type compound

Author(s) -

Masaru Mochizuki,

Tatsunari Inoue,

Katsunori Yamanishi,

Shiori Koike,

Mitsuru Kondo,

Liang Zhang,

Hiromi Aoki

Publication year - 2014

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c4dt02900c

Subject(s) - perchlorate , ion , molecule , inorganic chemistry , chemistry , materials science , organic chemistry

Reaction of CuSO4·5H2O with 1,3-bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene (m-bbitrb) provides a new positively charged M2L4 type molecule, [SO4⊂Cu2(m-bbitrb)4]SO4. This compound includes SO4(2-) inside and outside the cationic cage. Despite this compound being insoluble in water, it shows highly efficient perchlorate removal activity from water by the exchange with SO4(2-) outside the cage.

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