Interactions between halide anions and interfacial water molecules in relation to the Jones–Ray effect | Zendy

Khoi Tan Nguyen | Zendy; Anh V. Nguyen | Zendy; Geoffrey M. Evans | Zendy

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Interactions between halide anions and interfacial water molecules in relation to the Jones–Ray effect

Author(s) -

Khoi Tan Nguyen,

Anh V. Nguyen,

Geoffrey M. Evans

Publication year - 2014

Publication title -

physical chemistry chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.053

H-Index - 239

eISSN - 1463-9084

pISSN - 1463-9076

DOI - 10.1039/c4cp03629h

Subject(s) - halide , molecule , relation (database) , chemical physics , chemistry , materials science , computational chemistry , inorganic chemistry , organic chemistry , database , computer science

The Jones-Ray effect is shown to be governed by a different mechanism to enhanced anion adsorption. Halide ions at sub-molar concentrations are not exposed to the vapour phase; instead their first-solvating shell intimately interacts with the outmost water layer. Our novel proposal opens challenges for predicting related interfacial phenomena consistently.

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