Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO | Zendy

Noémie Elgrishi | Zendy; Matthew B. Chambers | Zendy; Vincent Artero | Zendy; Marc Fontecave | Zendy

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Terpyridine complexes of first row transition metals and electrochemical reduction of CO₂ to CO

Author(s) -

Noémie Elgrishi,

Matthew B. Chambers,

Vincent Artero,

Marc Fontecave

Publication year - 2014

Publication title -

physical chemistry chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.053

H-Index - 239

eISSN - 1463-9084

pISSN - 1463-9076

DOI - 10.1039/c4cp00451e

Subject(s) - terpyridine , homoleptic , transition metal , electrochemistry , chemistry , electrocatalyst , inorganic chemistry , materials science , catalysis , crystallography , nanotechnology , metal , electrode , organic chemistry

Homoleptic terpyridine complexes of first row transition metals are evaluated as catalysts for the electrocatalytic reduction of CO2. Ni and Co-based catalytic systems are shown to reduce CO2 to CO under the conditions tested. The Ni complex was found to exhibit selectivity for CO2 over proton reduction while the Co-based system generates mixtures of CO and H2 with CO : H2 ratios being tuneable through variation of the applied potential.

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