Carborane functionalization of the aromatic network in chemically-synthesized graphene | Zendy

Jan Kahlert | Zendy; Aditya Rawal | Zendy; James M. Hook | Zendy; Louis M. Rendina | Zendy; Mohammad Choucair | Zendy

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Carborane functionalization of the aromatic network in chemically-synthesized graphene

Author(s) -

Jan Kahlert,

Aditya Rawal,

James M. Hook,

Louis M. Rendina,

Mohammad Choucair

Publication year - 2014

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c4cc04521a

Subject(s) - surface modification , graphene , carborane , boron , conjugated system , x ray photoelectron spectroscopy , chemistry , nuclear magnetic resonance spectroscopy , spectroscopy , combinatorial chemistry , materials science , photochemistry , nanotechnology , organic chemistry , chemical engineering , polymer , engineering , physics , quantum mechanics

The conjugated aromatic system of graphene was used to trap the reactive, boron-rich 1,2-carborane cluster. Functionalization of the graphene surface was confirmed by solid-state MAS (11)B NMR spectroscopy and quantified by X-ray photoelectron spectroscopy. This work represents the first confirmed example of direct functionalization of a graphene lattice with carboranes.

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