Potential-driven molecular tiling of a charged polycyclic aromatic compound | Zendy

Kang Cui | Zendy; Oleksandr Ivasenko | Zendy; Kunal S. Mali | Zendy; Dongqing Wu | Zendy; Xinliang Feng | Zendy; Kläus Müllen | Zendy; Steven De Feyter | Zendy; Stijn F. L. Mertens | Zendy

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Potential-driven molecular tiling of a charged polycyclic aromatic compound

Author(s) -

Kang Cui,

Oleksandr Ivasenko,

Kunal S. Mali,

Dongqing Wu,

Xinliang Feng,

Kläus Müllen,

Steven De Feyter,

Stijn F. L. Mertens

Publication year - 2014

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c4cc04189e

Subject(s) - cationic polymerization , scanning tunneling microscope , supramolecular chemistry , in situ , materials science , electrochemistry , quantum tunnelling , chemical physics , crystallography , nanotechnology , chemistry , optoelectronics , crystal structure , organic chemistry , electrode , polymer chemistry

Using in situ electrochemical scanning tunnelling microscopy (EC-STM), we demonstrate fully reversible tuning of molecular tiling between self-assembled structures with supramolecular motifs containing 2, 3, 4, 6 or 7 tectons. The structures can be explained by electrocompression of the cationic adlayer at the solid-liquid interface.

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