Synthesis and characterization of a mercury-containing trimetalloboride | Zendy

Rüdiger Bertermann | Zendy; Holger Braunschweig | Zendy; William C. Ewing | Zendy; Thomas Krämer | Zendy; Ashwini K. Phukan | Zendy; Alfredo Vargas | Zendy; Christine Werner | Zendy

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Synthesis and characterization of a mercury-containing trimetalloboride

Author(s) -

Rüdiger Bertermann,

Holger Braunschweig,

William C. Ewing,

Thomas Krämer,

Ashwini K. Phukan,

Alfredo Vargas,

Christine Werner

Publication year - 2014

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c4cc01246a

Subject(s) - mercury (programming language) , chemistry , boron , chloride , atom (system on chip) , inorganic chemistry , crystallography , organic chemistry , computer science , programming language , embedded system

The reaction of phenylmercuric chloride with an anionic dimanganese borylene (Li(+)[Cp2(CO)4Mn2B](-)) led to the formation of a trimetalloboride featuring the first reported bond between mercury and a non-cluster boron atom. Examination by (199)Hg NMR indicated (11)B-(199)Hg scalar coupling. Theoretical calculations indicated the nature of bonding to be σ-donation from a B-Mn π-orbital to Hg, in conjunction with weak Hgd→π* back-donation.

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