Polyterpenes by ring opening metathesis polymerization of caryophyllene and humulene | Zendy

Étienne Grau | Zendy; Stefan Mecking | Zendy

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Polyterpenes by ring opening metathesis polymerization of caryophyllene and humulene

Author(s) -

Étienne Grau,

Stefan Mecking

Publication year - 2013

Publication title -

green chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.221

H-Index - 221

eISSN - 1463-9270

pISSN - 1463-9262

DOI - 10.1039/c3gc40300a

Subject(s) - humulene , polymerization , ring opening metathesis polymerisation , metathesis , polymer , caryophyllene , glass transition , materials science , romp , polymer chemistry , chemistry , organic chemistry , chromatography , essential oil

International audienceRing opening metathesis polymerization of the natural sesquiterpenes caryophyllene and humulene, optionally complemented by exhaustive post-polymerization hydrogenation, yields non-crosslinked linear polymers with unprecedented microstructures reflecting the specific scaffolds of the feedstocks and with low glass transition temperatures in the range from -15 to -50 degrees C

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