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A highly porous three-dimensional aluminum phosphonate with hexagonal channels: synthesis, structure and adsorption properties
Author(s) -
SiFu Tang,
Jinjun Cai,
Liangjun Li,
Xiaoxia Lv,
Chao Wang,
Xuebo Zhao
Publication year - 2013
Publication title -
dalton transactions
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.98
H-Index - 184
eISSN - 1477-9234
pISSN - 1477-9226
DOI - 10.1039/c3dt53167h
Subject(s) - phosphonate , adsorption , hexagonal crystal system , materials science , aluminium , porosity , chemical engineering , porous medium , nanotechnology , crystallography , chemistry , composite material , organic chemistry , engineering
A 3D porous aluminum(III) trisphosphonate, constructed from 1D inorganic aluminum phosphate chains and tripodal organic linkers, contains large hexagonal channels (1.24 nm in diameter) and a highly accessible void (50.3%) which allow it to have a fast and relatively high uptake of H2, N2 and CO2.

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