Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis | Zendy

Andrés F. Cardozo | Zendy; Éric Manoury | Zendy; Carine JulcourLebigue | Zendy; JeanFrançois Blanco | Zendy; Henri Delmas | Zendy; Florence Gayet | Zendy; Rinaldo Poli | Zendy

Open Access

Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis

Author(s) -

Andrés F. Cardozo,

Éric Manoury,

Carine JulcourLebigue,

JeanFrançois Blanco,

Henri Delmas,

Florence Gayet,

Rinaldo Poli

Publication year - 2013

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c3dt33082f

Subject(s) - hydroformylation , copolymer , catalysis , styrene , polymer chemistry , phosphine , polystyrene , chemistry , polymer , materials science , rhodium , organic chemistry

Well defined star copolymers have been prepared by copper-catalyzed atom transfer radical copolymerization of styrene and styryldiphenylphosphine starting from a modified Boltorn™ H30 multifunctional initiator. These polymers and an analogue obtained by debromination of the arm ends with nBu3SnH have been used in combination with [Rh(acac)(CO)2] for the homogeneous phase hydroformylation of 1-octene.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research