Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation | Zendy

Miguel Peixoto de Almeida | Zendy; Luísa M. D. R. S. Martins | Zendy; Sónia A. C. Carabineiro | Zendy; Tobias Lauterbach | Zendy; Frank Röminger | Zendy; A. Stephen K. Hashmi | Zendy; Armando J. L. Pombeiro | Zendy; José L. Figueiredo | Zendy

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Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation

Author(s) -

Miguel Peixoto de Almeida,

Luísa M. D. R. S. Martins,

Sónia A. C. Carabineiro,

Tobias Lauterbach,

Frank Röminger,

A. Stephen K. Hashmi,

Armando J. L. Pombeiro,

José L. Figueiredo

Publication year - 2013

Publication title -

catalysis science and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.635

H-Index - 115

eISSN - 2044-4761

pISSN - 2044-4753

DOI - 10.1039/c3cy00552f

Subject(s) - cyclohexanol , cyclohexane , cyclohexanone , catalysis , homogeneous , aqueous solution , chemistry , carbon fibers , inorganic chemistry , medicinal chemistry , organic chemistry , materials science , physics , thermodynamics , composite number , composite material

Gold(III) complexes of type [AuCl2{eta(2)-RC(R'pz)(3)}]Cl [R = R' = H (1), R = CH2OH, R' = H (2) and R = H, R' = 3,5-Me-2(3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions

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