Growth of large single MOF crystals and effective separation of organic dyes | Zendy

Lina Li | Zendy; Fuxing Sun | Zendy; Jiangtao Jia | Zendy; Tsolmon Borjigin | Zendy; Guangshan Zhu | Zendy

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Growth of large single MOF crystals and effective separation of organic dyes

Author(s) -

Lina Li,

Fuxing Sun,

Jiangtao Jia,

Tsolmon Borjigin,

Guangshan Zhu

Publication year - 2013

Publication title -

crystengcomm

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.813

H-Index - 132

ISSN - 1466-8033

DOI - 10.1039/c3ce40137e

Subject(s) - thionine , materials science , chemical engineering , separation (statistics) , chromatography , chemistry , computer science , machine learning , engineering , electrode , electrochemistry

Through the optimization of synthesis conditions, we obtained large Cu-3(BTC)(2) crystals with a diameter of 2-4 mm. Such large crystals could be utilized as "chromatographic columns" for effective separation of organic dyes such as thionine (TH) and pyronin B (PB). It was found that the concentration of hydron was the key factor to obtain the large pure crystals. This strategy could be used to grow other hydrophilic MOFs.Full Tex

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