High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites | Zendy

Liangjun Li | Zendy; SiFu Tang | Zendy; Chao Wang | Zendy; Xiaoxia Lv | Zendy; Min Jiang | Zendy; Huaizhi Wu | Zendy; Xuebo Zhao | Zendy

Open Access

High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

Author(s) -

Liangjun Li,

SiFu Tang,

Chao Wang,

Xiaoxia Lv,

Min Jiang,

Huaizhi Wu,

Xuebo Zhao

Publication year - 2013

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c3cc48275h

Subject(s) - adsorption , metal organic framework , extraction (chemistry) , lewis acids and bases , chemistry , inorganic chemistry , chemical engineering , organic chemistry , catalysis , engineering

A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4 and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites.

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