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Improvement of hydrothermal stability of zeolitic imidazolate frameworks
Author(s) -
Xinlei Liu,
Yanshuo Li,
Yujie Ban,
Yuan Peng,
Hua Jin,
Helge Bux,
Longya Xu,
Jürgen Caro,
Weishen Yang
Publication year - 2013
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c3cc45308a
Subject(s) - hydrothermal circulation , imidazolate , adsorption , zeolitic imidazolate framework , metal organic framework , chemical engineering , ligand (biochemistry) , hydrolysis , chemistry , shell (structure) , hydrothermal synthesis , membrane , materials science , inorganic chemistry , organic chemistry , biochemistry , receptor , engineering , composite material
The metal-organic framework ZIF-8, which undergoes hydrolysis under hydrothermal conditions, is endowed with high water-resistance after a shell-ligand-exchange-reaction. The stabilized ZIF-8 retains its structural characteristics with improved application performances in adsorption and membrane separation.

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