Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions | Zendy

Katsunori Yamanishi | Zendy; Takeshi Yairi | Zendy; Keisuke Suzuki | Zendy; Mitsuru Kondo | Zendy

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Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions

Author(s) -

Katsunori Yamanishi,

Takeshi Yairi,

Keisuke Suzuki,

Mitsuru Kondo

Publication year - 2013

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c3cc44558e

Subject(s) - porphyrin , amide , chemistry , ring (chemistry) , catalysis , ligand (biochemistry) , molecule , carbon fibers , small molecule , organic chemistry , receptor , materials science , biochemistry , composite number , composite material

The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described.

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