The first purification and unequivocal characterization of the radical form of the carbon-centered quinone ketoxy radical adduct | Zendy

ChunHua Huang | Zendy; Guoqiang Shan | Zendy; Li Mao | Zendy; Balaraman Kalyanaraman | Zendy; Hao Qin | Zendy; Fu-Rong Ren | Zendy; BenZhan Zhu | Zendy

Open Access

The first purification and unequivocal characterization of the radical form of the carbon-centered quinone ketoxy radical adduct

Author(s) -

ChunHua Huang,

Guoqiang Shan,

Li Mao,

Balaraman Kalyanaraman,

Hao Qin,

Fu-Rong Ren,

BenZhan Zhu

Publication year - 2013

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c3cc42732c

Subject(s) - adduct , quinone , chemistry , high performance liquid chromatography , spin trapping , carbon fibers , resolution (logic) , characterization (materials science) , hydroxyl radical , photochemistry , chromatography , radical , organic chemistry , materials science , nanotechnology , artificial intelligence , composite number , computer science , composite material

We found, unexpectedly, that the radical form of the carbon-centered quinone ketoxy radical adduct with a recently developed spin-trapping agent BMPO can not only be directly detected and identified using HPLC/high resolution MS, but can also be isolated and purified using semi-preparative HPLC, enabling direct observation of its clean 6-line ESR signal.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research